Ch06 Nonferrous Metals & Alloys
MECH306
Nonferrous metals cost more than ferrous but offer corrosion resistance, high thermal/electrical conductivity, low density, and easy fabrication.
Aluminum & Alloys
- Uses: packaging (cans, foil), construction, transportation (aircraft ~80% Al), electrical conductors, cookware.
- Temper designations: H = strain-hardened (wrought), O = annealed, T = heat-treated.
- 7075 (aircraft): very high strength but low machinability/weldability.
- Forms: wrought (rolling, extrusion, drawing) and cast. Designations: 4 digits (wrought) or 4 digits with a dot (cast); first digit = major alloying element.
- Production: ore = hydrated alumina; DC electrolysis — Al at cathode, O₂ at anode; energy-intensive; second only to iron in tonnage.
Magnesium & Alloys
- Lightest structural metal (≈ 1.78 g/cm³); good vibration damping.
- From seawater (electrolytic/thermal reduction). Aircraft, missiles, luggage, bicycles, sporting goods, high-speed machinery (low inertia), notebook housings (easy die casting).
Copper & Alloys
- Excellent electrical/heat conductor; good corrosion resistance.
- Brass = Cu + Zn; Bronze = Cu + Sn.
- Electrical/electronic gear, plumbing, heat exchangers, cookware.
Nickel & Alloys
- Major alloying element in stainless steels (strength, toughness, corrosion resistance).
- High-T uses: jet engines, rockets, nuclear plants, chemical/food processing.
- Inconel (Ni–Cr) and Monel (Ni–Cu): UTS up to ~1400 MPa; Invar (Fe–Ni): very low thermal sensitivity.
Superalloys (high-temperature)
- Resist corrosion, thermal/mechanical fatigue & shock, creep, erosion at high T.
- Three bases: iron-, cobalt-, nickel-base; minor additions Al, W, Ti.
- Service up to ~1000°C (structural), ~1200°C (non-load-bearing). Jet engines, gas turbines.
Titanium & Alloys
- Expensive; high strength/density ratio; high corrosion resistance (room & high T).
- Properties sensitive to small composition changes. Jet engines, racing cars, submarine hulls, orthopedic implants.
Refractory Metals (high melting point)
- Mo ( 2610°C), Nb, W ( 3410°C), Ta ( 2996°C).
- Best high-T strength retention; service ~1100–2200°C. Rocket engines, gas turbines, aerospace, electronics, nuclear, tooling.
Low-Melting Alloys
- Lead: high density, corrosion resistance (oxide film), soft/ductile, low strength; piping, vibration/sound damping, X-ray shielding; toxic.
- Zinc: (1) galvanizing steel — Zn is anodic, protects steel even if scratched; (2) alloying (brass).
- Tin: protective coating on steel (tin plate) for food cans; but if scratched the steel corrodes (Zn is better for that).
Precious Metals
Gold, silver, platinum (soft, ductile, high-T corrosion resistance) — spark plugs, thermocouples, dental, electrochemical.
Shape-Memory Alloys
Return to original shape on heating after room-temperature deformation. Typical 55% Ni, 45% Ti; temperature-sensitive actuators, eyeglass frames, connectors, clamps, seals.