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Ahmet Çelik
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Ch06 Nonferrous Metals & Alloys

MECH306

Nonferrous metals cost more than ferrous but offer corrosion resistance, high thermal/electrical conductivity, low density, and easy fabrication.

Aluminum & Alloys

  • Uses: packaging (cans, foil), construction, transportation (aircraft ~80% Al), electrical conductors, cookware.
  • Temper designations: H = strain-hardened (wrought), O = annealed, T = heat-treated.
  • 7075 (aircraft): very high strength but low machinability/weldability.
  • Forms: wrought (rolling, extrusion, drawing) and cast. Designations: 4 digits (wrought) or 4 digits with a dot (cast); first digit = major alloying element.
  • Production: ore = hydrated alumina; DC electrolysis — Al at cathode, O₂ at anode; energy-intensive; second only to iron in tonnage.

Magnesium & Alloys

  • Lightest structural metal (≈ 1.78 g/cm³); good vibration damping.
  • From seawater (electrolytic/thermal reduction). Aircraft, missiles, luggage, bicycles, sporting goods, high-speed machinery (low inertia), notebook housings (easy die casting).

Copper & Alloys

  • Excellent electrical/heat conductor; good corrosion resistance.
  • Brass = Cu + Zn; Bronze = Cu + Sn.
  • Electrical/electronic gear, plumbing, heat exchangers, cookware.

Nickel & Alloys

  • Major alloying element in stainless steels (strength, toughness, corrosion resistance).
  • High-T uses: jet engines, rockets, nuclear plants, chemical/food processing.
  • Inconel (Ni–Cr) and Monel (Ni–Cu): UTS up to ~1400 MPa; Invar (Fe–Ni): very low thermal sensitivity.

Superalloys (high-temperature)

  • Resist corrosion, thermal/mechanical fatigue & shock, creep, erosion at high T.
  • Three bases: iron-, cobalt-, nickel-base; minor additions Al, W, Ti.
  • Service up to ~1000°C (structural), ~1200°C (non-load-bearing). Jet engines, gas turbines.

Titanium & Alloys

  • Expensive; high strength/density ratio; high corrosion resistance (room & high T).
  • Properties sensitive to small composition changes. Jet engines, racing cars, submarine hulls, orthopedic implants.

Refractory Metals (high melting point)

  • Mo (TmT_m 2610°C), Nb, W (TmT_m 3410°C), Ta (TmT_m 2996°C).
  • Best high-T strength retention; service ~1100–2200°C. Rocket engines, gas turbines, aerospace, electronics, nuclear, tooling.

Low-Melting Alloys

  • Lead: high density, corrosion resistance (oxide film), soft/ductile, low strength; piping, vibration/sound damping, X-ray shielding; toxic.
  • Zinc: (1) galvanizing steel — Zn is anodic, protects steel even if scratched; (2) alloying (brass).
  • Tin: protective coating on steel (tin plate) for food cans; but if scratched the steel corrodes (Zn is better for that).

Precious Metals

Gold, silver, platinum (soft, ductile, high-T corrosion resistance) — spark plugs, thermocouples, dental, electrochemical.

Shape-Memory Alloys

Return to original shape on heating after room-temperature deformation. Typical 55% Ni, 45% Ti; temperature-sensitive actuators, eyeglass frames, connectors, clamps, seals.