Ch03 Physical Properties
MECH306
Beyond mechanical behavior, design must weigh density, melting point, specific heat, thermal & electrical conductivity, thermal expansion, and corrosion resistance.
Density
- Density = mass per unit volume; weight saving is critical for aircraft/aerospace.
- Specific strength = strength-to-weight ratio. Titanium has the highest among metals; fibers beat most metals.
- High-speed equipment (printing, textiles) favors low-density metals (e.g. magnesium) to cut inertial forces.
Melting Point
- Depends on the energy needed to separate atoms.
- A pure metal has a definite melting point; an alloy melts over a range.
Specific Heat
- Energy to raise unit mass by one degree.
- Temperature rise in forming/machining depends on the work done and the specific heat.
- Excessive temperature rise hurts surface finish & dimensional accuracy, increases tool/die wear, and can cause adverse metallurgical changes.
Thermal Conductivity
- Heat from plastic deformation/friction must be conducted away fast enough to avoid a severe temperature rise.
- Titanium machines poorly largely because of its very low thermal conductivity.
Thermal Expansion
- The coefficient of thermal expansion is roughly inversely proportional to melting point; alloying has only a minor effect.
- Shrink fits exploit it: heat a part with a hole, slip it over a cool shaft; on cooling it shrinks into an integral assembly.
Electrical Properties
- Resistivity = inverse of conductivity; high-resistivity materials are dielectrics / insulators.
- Superconductors: ~zero resistivity below a critical temperature (near 0 K; record ≈150 K = −123°C). Promise for high-power magnets, power lines, electronics.
- Semiconductors (Si, Ge, GaAs): conductivity is highly sensitive to temperature and dopant type/level (e.g. P, B in Si).
- Piezoelectric effect: reversible coupling of elastic strain and electric field (quartz, some ceramics) — used in transducers, strain gages, sonar, microphones.
Corrosion Resistance
- Corrosion = deterioration of metals/ceramics; in plastics the analog is degradation.
- Important in chemical, food, and petroleum industries; corrosion lowers strength and structural integrity (U.S. cost ≈ $200 billion/yr).
- Steels and cast irons resist poorly → need coatings/surface treatments (Ch33).
- Stainless steels form a protective chromium-oxide film (passivation).